Publications


Title : Carbon Number Study on Self-Assmble Mechanisms in AOT / D2O / n-alkane Microemulsion Systems

Language: English
Type: Article
Authors: Michihiro Nagao, Hideki Seto and Youhei Kawabata
Journal: Journal of the Physical Society of Japan
ISSN: 0031-9015
Volume: 70
Number: Supplement A
Year: 2001
Actual year: 2001
Pages: 335-337
Abstract: We performed small angle neutron scattering (SANS) experiments in ternary microemulsion systems, consisting of AOT (dioctyl sulfosuccinate sodium salt), water and 3 kinds of n-alkane (hexane, octane and decane). The observed SANS profile was analyzed by two different models; one is a traditional Ginzburg-Landau model and the other is a product of a particle form factor and a structure factor. In the second model, a particle form factor of polydisperse spherical droplets and a structure factor of hard-sphere with the adhesive inter-droplet potential were used. The first model explained the broad peak profile only at low Q range and the second did at all the measured Q range. From the fitting by the second model, the stickiness parameter was estimated and it increased with increasing the carbon number of n-alkane. This result indicates that the interaction between droplets increases with increasing carbon number. This tendency is almost the same as increasing pressure.

"Carbon Number Study on Self-Assmble Mechanisms in AOT / D2O / n-alkane Microemulsion Systems"

Michihiro Nagao, Hideki Seto and Youhei Kawabata, Journal of the Physical Society of Japan, 70, 335-337 (2001)