Publications
Title:
Core-shell structures in single flexible-semiflexible block copolymers: Finding the free energy minimum for the folding transition
| Language: | English |
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| Type: | Article |
| Authors: | Natsuhiko Yoshinaga and Kenichi Yoshikawa |
| Editors: | |
| Journal: | Journal of Chemical Physics |
| ISSN: | 0021-9606 |
| Volume: | 127 |
| Number: | 4 |
| Month: | 7 |
| Year: | 2007 |
| Actual year: | 2007 |
| Pages: | 044902/1–5 |
| doi: | 10.1063/1.2753838 |
| bibtex id: | 2007_JCP_Yoshinaga_07-13 |
| Abstract: | We investigate the folding transition of a single diblock copolymer consisting of a semiflexible and a flexible block. We obtain a Saturn-shaped core-shell conformation in the folded state, in which the flexible block forms a core and the semiflexible block wraps around it. We demonstrate two distinctive features of the core-shell structures: (i) The kinetics of the folding transition in the copolymer are significantly more efficient than those of a semiflexible homopolymer. (ii) The core-shell structure does not depend on the transition pathway. (c) 2007 American Institute of Physics. |
| Acknowledgment: |
| 2007 | |
| "Core-shell structures in single flexible-semiflexible block copolymers: Finding the free energy minimum for the folding transition" Natsuhiko Yoshinaga and Kenichi Yoshikawa, Journal of Chemical Physics, 127(4), 044902/1–5 (2007) | detail publisher doi:10.1063/1.2753838 |
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